The reaction of chloromethylsilanes with amines, hexamethyldisilazanes, and silylcarhamates
โ Scribed by A. D. Kirilin; N. B. Sokova; E. A. Chernyshev
- Book ID
- 112388085
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 335 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
P 4 S 10 reacts with (Me 3 Si) 2 NH, to give SP(NHSi-Me 3 ) x (SSiMe 3 ) 3โซืโฌx , where x โซืกโฌ 0-3. These species were shown by 31 P NMR spectroscopy to subsequently form cyclic and linear condensation products. The molecular structure of a linear trimer (Me 3 SiNH)P(S)[(l-NH)P(S)(NHSiMe 3 ) 2 ] 2 , 1
Quantum chemical calculations of the reaction of hexamethyldisilazane with silica indicates a two-step mechanism. The first, rate-determining step results in trimethylsilylation of a surface silanol and formation of trimethylaminosilane. The second step involves reaction of a trimethylaminosilane re