## Abstract Dimethoxycarbene (1a) and methoxy(2,2,2โtrifluoroethoxy)โcarbene (1b) were generated in benzene solution by thermolysis of the corresponding 2,2โdialkoxyoxadiazolines 7. The carbenes were trapped by intermolecular reaction with a variety of cyclic anhydrides 8. The products 9 are formal
โฆ LIBER โฆ
The reaction of carbonylcarbene with cyclic ethers. Competition between deoxygenation and insertion into the carbon-oxygen bond
โ Scribed by Forbus, Thomas R.; Birdsong, Philip A.; Shevlin, Philip B.
- Book ID
- 126952613
- Publisher
- American Chemical Society
- Year
- 1978
- Tongue
- English
- Weight
- 490 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0002-7863
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su?n?M?y a-Ltth~anon of dthydrofuran, benzofuran, and dlhydropyran followed by treatment with vanous organohthtums stereoselecnvely produces m gwd ytelds the conespondmg rmg-opened Q-alkenylhthtums. t e , (E)-B(or y)-hydroxy-to-alkenyl-co-hthtoalkenes, the hthtum atom of which can be readtly replace