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ChemInform Abstract: Carbon-Oxygen Bond Insertion in the Reaction of Dialkoxycarbenes with Anhydrides.

✍ Scribed by D. L. POLE; J. WARKENTIN

Book ID
112027617
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Carbon–oxygen bond insertion in the reac
Carbon–oxygen bond insertion in the reaction of dialkoxycarbenes with anhydrides
✍ Pole, David L. ;Warkentin, John 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 881 KB

## Abstract Dimethoxycarbene (1a) and methoxy(2,2,2‐trifluoroethoxy)‐carbene (1b) were generated in benzene solution by thermolysis of the corresponding 2,2‐dialkoxyoxadiazolines 7. The carbenes were trapped by intermolecular reaction with a variety of cyclic anhydrides 8. The products 9 are formal