THE REACTION OF CARBON DISULFIDE ON PARA-PHENYLENEDIAMINE
โ Scribed by Bolser, C. Ernest; Hartshorn, Elden B.
- Book ID
- 127157384
- Publisher
- American Chemical Society
- Year
- 1923
- Tongue
- English
- Weight
- 484 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
A new type of compound (2) was obtained from the reaction of a metsllated thiourea with carbon disulfide followed by methylatlon. A reaction mechanism involving a rearrangement of dimethylamino group was suggested.
Ye wish to report the hitherto unknown reaotlcm of benzyne with carbon dleulilde to @~a thlQanlSOle, thloqgenol and dlnhenyl sulfide. Hetalllo sodlum and liquid amnontd were stirred for 1 hr and, Into the resultant dark-violet solution was added an appropriate amount of carbon dlsul?lde durlw 7 min
Recent publications concerned with several different resonance-stabilized sulfonlum ylldes have covered their preparation and spectral properties and synthetic utility but relatively few of thlooarbonyl-stablllzed ylldes have been reported'). We wish to report here a synthesis of some dlthloformate-