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The reaction of benzyltriphenylarsonium ylides with aldehydes. A note about the mechanism of the wittig reaction

✍ Scribed by René Broos; Marc J. O. Anteunis

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
438 KB
Volume
97
Category
Article
ISSN
0037-9646

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In this study, we describe the results of ab initio (HF and MP2) and MNDO-PM3 calculations on the model reactions of unstabilized (Me 3 P‫ס‬CH-CH 3 ), semistabilized (Me 3 P‫ס‬CH-CϵCH), and stabilized (Me 3 P‫ס‬CH-CϵN) ylides with acetaldehyde to form their respective Z and E olefins and trimethylph