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ChemInform Abstract: Theoretical Study of the Mechanism of the Wittig Reaction: Ab initio and MNDO-PM3 Treatment of the Reaction of Unstabilized, Semistabilized, and Stabilized Ylides with Acetaldehyde.

✍ Scribed by A. A. RESTREPO-COSSIO; H. CANO; F. MARI; C. A. GONZALEZ


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
29
Category
Article
ISSN
0931-7597

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Theoretical study of the mechanism of th
✍ Albeiro A. Restrepo-Cossio; Hermisul Cano; Frank MarΓ­; Carlos A. Gonzalez πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 313 KB πŸ‘ 2 views

In this study, we describe the results of ab initio (HF and MP2) and MNDO-PM3 calculations on the model reactions of unstabilized (Me 3 P‫ב‬CH-CH 3 ), semistabilized (Me 3 P‫ב‬CH-CΟ΅CH), and stabilized (Me 3 P‫ב‬CH-CΟ΅N) ylides with acetaldehyde to form their respective Z and E olefins and trimethylph