The reaction of B-vinylic- and B-alkyl-9-borabicyclo[3.3.1]nonane derivatives with ethyl diazoacetate and diazoacetone
โ Scribed by J. Hooz; D.M. Gunn
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 174 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Numerous studies have attested to the synthetic value of trialkylboranes 1 as intermediates for the alklation of ylides , carbanions 2 , and diaso com-
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The reaction of acetic acid with ate-canplexes prepared from B-alkyl-9-borabicyclo-[3,3,l]nonanes and l-lithio-1-methoxyallene gives corresponding l-alkyl-1-methoxycyclopropanes good yields. in Recently, many reports have appeared dealing with new applications of alkali metal organoborates for the s
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