The reaction of atomic hydrogen with NO2
โ Scribed by John E. Spencer; G.P. Glass
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 618 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
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The mechamsm of rexnon of atomic hydrogen wth CH,Br has been exammed by product analysis m a static system In a vessel coaled wrh NaOH to remove HBr. quantum ytelds close IO u-my are found for C,H, formatIon\_ H+CH,Br + CH, + HBr XH, -c C2 H, The reaction scheme 1s modelled by assuming that surLxe l
Hydrogen atoms, generated by the mercury (3P1) sensitization of Hz, were allowed to react with dimethyldisulfide in the temperature range of 25-155'C. The only retrievable product is methanethiol, formed in the primary metathetical reaction H + CH3SSCH3 k,' CH3SH t CH3S. The intermediacy of thiyl ra