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The Reaction of Alkenes with Triangulo-Clusters [Pt3(μ-CO)3(PR3)3]

✍ Scribed by Renzo Ros; Giacomo Facchin; Augusto Tassan; Raymond Roulet; Gàbor Laurenczy; Ferenc Lukacs

Book ID
110351732
Publisher
Springer
Year
2001
Tongue
English
Weight
316 KB
Volume
12
Category
Article
ISSN
1040-7278

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## Dedicated to Prof. Huns-Georg uon Schnering on the occasion of his 60th birthday (1 7.V. 9 I) The cluster compounds [Pt,(,u-CO),(PR,),] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX,, and Group XIII, MX,, to form cluster compounds of the composition [{MX,}{Pt3(,u-

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Reactions of Pt3Ru6(CO)2(μ3-H)(μ-H)3 with Phos[phanes — The Synthesis and Structural Characterizations of [Pt(PMe3)3H][Pt3Ru6(CO)21(μ3-H)(μ-H)2] and [Pt3Ru6(CO)20(PPh3)(μ-H)3(μ3H)]
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The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d