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The Reaction of 4-Hydroperoxy-2,4,6-trimethylcyclohexa-2,5-dienone with Acetaldehyde. Formatino of the Bis(peroxyacetal)

✍ Scribed by Charles W. Jefford; Gérald Bernardinelli; Ernest C. McGoran

Publisher: John Wiley and Sons
Year: 1984
Tongue: German
Weight: 311 KB
Volume: 67
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19840670733

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✦ Synopsis

Abstract

The reaction of 4‐hydroperoxy‐2,4,6‐trimethylcyclohexa‐2,5‐dienone with acetaldehyde using trimethylsilyl trifluoromethanesulfonate as catalyst gives 1,1′‐bis[(1,3,5‐trimethyl‐4‐oxo‐2,5‐cyclohexadienyl) peroxy]diethyl ether (7) in 70% yield. The structure of this unusual acetal was determined by X‐ray analysis.

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