In acidic solution, L-ascorbic acid undergoes decarboxylation with the formation of 2-furancarbaldehyde, suggesting that a five-carbon fragment is probably produced as an intermediate in the reaction. Isbell' proposed 3-deoxy-L-glycero-pentos-2-ulose (3-deoxy+xylosone, 1) as a reaction intermediate.
✦ LIBER ✦
The reaction of 3-deoxy-d-glycero-pentos-2-ulose (“3-deoxyxylosone”) with aminoguanidine
✍ Scribed by Jan Hirsch; John W. Bayness; James A. Blackledge; Milton S. Feather
- Book ID
- 107726035
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 203 KB
- Volume
- 220
- Category
- Article
- ISSN
- 0008-6215
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## Note The oxidation of 3-deoxy-D-erythro-hexos-2-ulose ("3-deoxyglucosone") to 3deoxy-D-erythro-2-hexulosonic acid ("2-keto-3-deoxy-D-gluconate") by D-glucase oxidase" 3-Deoxy-D-erJ,t/zro-3-hexulosonic acid ("2-heto-3-deoxy-D-glucollic acid", 2) is a bacterial metabolite that may arise from D-gl