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The reaction of 3-(1-imidazolyl)-2-alken-1-ones with nucleophiles

โœ Scribed by C. Kashima; T. Tajima; M. Shimizu; Y. Omote

Book ID
112126909
Publisher
Journal of Heterocyclic Chemistry
Year
1982
Tongue
English
Weight
270 KB
Volume
19
Category
Article
ISSN
0022-152X

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โœ Lizi Yang; Ran Fang; Yongcheng Wang ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier ๐ŸŒ English โš– 540 KB

The mechanism of AuCl 3 -catalyzed synthesis of highly substituted furans from 2-(1-alkynyl)-2-alken-1-ones with nucleophiles have been investigated using density functional theory calculations done at the BHandHLYP/6-31G(d, p) (lanl2dz for Au) level of theory. Our calculations suggest that the firs