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The reaction between triethyl phosphite and diphenyliodonium salts. Formation of diethyl phenylphosphonate and 1,4-diiodobenzene.

โœ Scribed by A.G. Varvoglis


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
107 KB
Volume
13
Category
Article
ISSN
0040-4039

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Alkali metal salts of diethyl phosphites act as nucleophiles or electron donors in reactions with diethyl phosphorochloridate. Evidence is provided that formation of the direct P(IV) P(IV) bond proceeds via a single electron transfer process (SET) from phosphite anion to phosphorochloridate.

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## Abstract Treatment of 2โ€__tert__โ€butylโ€1โ€benzoselenopyrylium salts **1A** and 2โ€phenylโ€1โ€benzoselenopyrylium salts **1B** with an alkyl(phenyl)magnesium halide resulted in nucleophilic addition at the Cโ€4 position to give the corresponding 2,4โ€disubstituted 4__H__โ€selenochromenes **2A** and **2B