Alkali metal salts of diethyl phosphites act as nucleophiles or electron donors in reactions with diethyl phosphorochloridate. Evidence is provided that formation of the direct P(IV) P(IV) bond proceeds via a single electron transfer process (SET) from phosphite anion to phosphorochloridate.
โฆ LIBER โฆ
The reaction between triethyl phosphite and diphenyliodonium salts. Formation of diethyl phenylphosphonate and 1,4-diiodobenzene.
โ Scribed by A.G. Varvoglis
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 107 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
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