✦ LIBER ✦
Reinvestigation of the reaction between sodium diethyl phosphite and diethyl phosphorochloridate. Evidence for a SET process in the formation of a direct P(IV)P(IV) bond
✍ Scribed by Ryszard W Kinas; Andrzej Okruszek; Wojciech J Stec
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 195 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Alkali metal salts of diethyl phosphites act as nucleophiles or electron donors in reactions with diethyl phosphorochloridate. Evidence is provided that formation of the direct P(IV) P(IV) bond proceeds via a single electron transfer process (SET) from phosphite anion to phosphorochloridate.