๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The reaction between Na vapor and N2O at room temperature

โœ Scribed by R.E. Walker; J.E. Creeden


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
343 KB
Volume
21
Category
Article
ISSN
0010-2180

No coin nor oath required. For personal study only.

โœฆ Synopsis


The gas-phase reaction between Na metal vapor and NzO has been examined at near morn tempct;rturr in a fast-flow low ptesure reactor using pho.ometric methods. The reaction rate wab detcrminrd tn h k, = 7.6 x 10" rm3/mole set at 330ยฐC and gives an activation energy ofabout I IO0 cal/m& ohepn compared with published high-temperature rate data. The reactmn is ac,:ompanied by Na D-line rhem,. lutnh~escecence, the intensity of which is found to correspond to Naatom removal;? kinetic mcchsrurm Is suggested to explain this behavior.


๐Ÿ“œ SIMILAR VOLUMES


Room temperature rate coefficient for th
โœ J. N. Crowley; J. P. Burrows; G. K. Moortgat; G. Poulet; G. LeBras ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 507 KB

The molecular modulation spectroscopic technique was employed to study the kinetics of NO3 radicals produced in the 253.7 nm photolysis of flowing gas mixtures of HNO3/CH4/O2 at room temperature. By computer fitting of the NO, temporal behavior, a rate coefficient of (2.3 ? 0.7) x lo-'' cm3 molecule

A discharge-flow/chemiluminescence study
โœ Craig A. Taylor; Paul Marshall ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 321 KB

Discharge-Bow kinetic studies using NO1 chemiluminescence detection of 0 yielded a rate constant for OtSizHs of (6.Ok 1.0) x lo-r2 cm3 s-' at 295 K, where the 95% confidence interval includes both precision and accuracy. Insertion and abstraction mechanisms are discussed, and on the assumption that