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The reaction between HO and (H2O)n(n

✍ Scribed by Javier Gonzalez; Marc Caballero; Antoni Aguilar-Mogas; Miquel Torrent-Sucarrat; Ramon Crehuet; Albert Solé; Xavier Giménez; Santiago Olivella; Josep M. Bofill; Josep M. Anglada

Publisher: Springer
Year: 2010
Tongue: English
Weight: 550 KB
Volume: 128
Category: Article
ISSN: 1432-2234
DOI: 10.1007/s00214-010-0824-5

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The rate coeffkent of the H + HOz react1011 has been determmed as (5.0 r 1.3) X lo-" cm3 molecule-' S-I at 298 K by the use of laser magnetx resonance spectroscopy to determine the steady-state concentration of HO2 radicals in the reaction of atomic hydrogen wth molecular oxygen.

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## Radicalrecombination rates have been measured in fuel-lean H2/02/N2 fhmesat temperatures up to 3130'K. The observed rnres cannot be accoan:ed for in terms of termolecular reactions such as H f OH + in! -. Hz0 + hl and the occunence of an additional recumbination route, H + 02 + hI 5 HO? + &I,

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HO2 profiles in the thermal decomposition of H,02 in shock waves over the range 1000-1250 K were analyzed with respect to the reactions HO+HZOz+HOz+H20 (3) and HO+H0r~Hz0+02 (4). Reaction (3) shows a strong up-turn ofthe rate constant at temperatures near 800 K. Over the range 250-1250 K, k, can be

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## Abstract The interaction between molybdenum, atom, and dimer, with nitrous oxide has been investigated using density functional theory. The analysis of the potential energy surfaces for both reactions has revealed that a single molybdenum atom can activate the NO bond of N~2~O requiring a small

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The reaction between Na vapor and N2O at

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✍ R.E. Walker; J.E. Creeden 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 343 KB

The gas-phase reaction between Na metal vapor and NzO has been examined at near morn tempct;rturr in a fast-flow low ptesure reactor using pho.ometric methods. The reaction rate wab detcrminrd tn h k, = 7.6 x 10" rm3/mole set at 330°C and gives an activation energy ofabout I IO0 cal/m& ohepn compare