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The Reaction between Deuterium and 1-Butyne, 1,2-Butadiene, and 1,3-Butadiene on Palladium-on-Alumina Catalyst

โœ Scribed by Meyer, Edwin F.; Burwell, Robert L.


Book ID
125898071
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
876 KB
Volume
85
Category
Article
ISSN
0002-7863

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1,3-Disubstituted triazenes 3 are oxidized with ten-butyl hypochlorite to N-chlorotriazenes 4, which at low temperatures with antimony pentachloride afford 1,3-diaza-2-azoniaallene salts 5 as reactive intermediates. Cations 5 undergo cycloadditions to one or both double bonds of 1,3-butadienes to fu