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Mechanistic Studies of the Pyrolysis of 1,3-Butadiene, 1,3-Butadiene-1,1,4,4- d 4 , 1,2-Butadiene, and 2-Butyne by Supersonic Jet/Photoionization Mass Spectrometry

โœ Scribed by Chambreau, Steven D.; Lemieux, Jessy; Wang, Liming; Zhang, Jingsong


Book ID
125991391
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
204 KB
Volume
109
Category
Article
ISSN
1089-5639

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Formation of H and D atoms in pyrolysis
โœ V. S. Rao; Kunio Takeda; Gordon B. Skinner ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 606 KB

Highly dilute mixtures of 1,3-butadiene and 1,3-butadiene-1,1,4,4-d4 were pyrolyzed behind reflected and incident shock waves, respectively. Concentrations of H and D atoms were measured by resonance absorption spectroscopy. In the early stages of the reaction, nearly equal amounts of H and D were f