The reaction between 2,5-dialkylpyrroles and dichlorocarbene
✍ Scribed by A. Gambacorta; R. Nicoletti; S. Cerrini; W. Fedeli; G. Gavuzzo
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 698 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
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## Abstract The reaction of 4,5‐dihydro‐2‐morpholino‐ (and ‐2‐pyrrolidino)‐3‐furancarbonitriles 1a, c, d and 2a, c, d with dichlorocarbene gave 4‐(2,4‐pentadienoyl)morpholines 3a, c, d and 1‐(2,4‐pentadienoyl)pyrrolidines 4a, c, d. Similarly, the reaction of 4,5‐dihydro‐5‐methyl‐2‐morpholino‐ (and
The dissociation dynamics of CCI,-anions were studied under various internal energy conditions. This study involved the measurement of daughter-ion spectra and branching ratios and of the amount of kinetic energy released (KER) on the fragments. The competition between C and CI loss for CCI,ions cre