CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120Β°C in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an
The rate of the reactions of C2O radicals with H and H2
β Scribed by O. Horie; W. Bauer; R. Meuser; V.H. Schmidt; K.H. Becker
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 389 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The rate constants for the reactions C20 + H -products (1) and C20 + H2 + products ( 2) have been determined at room temperature by means of laser-induced fluorescence detection of C,O radicals, c oenerated either by the KrF excimer laser photolysis of C302, or by the reaction of C302 with 0 atoms. Values of kl = (3.7 f 1 .O) X lo-" cm3 s-l and k2 = (7 -A 3)
x lo-l3 cm3 s-t were obtained_
π SIMILAR VOLUMES
n-C3H70N0 was photolyzed with 366 nm radiation at -26, -3,23,55, 88, and 120Β°C in a static system in the presence of NO, Oz, and N 2 . The quantum yields of C2H5CH0, C z H 5 0 N 0 , and CH3CH0 were measured as a function of reaction conditions. The primary photochemical act is and it proceeds with
The rate coefficients for the gas-phase reactions of C,H,O;, and n-C3H,0, radicals with NO have been measured over the temperature range of (201 -403) K using chemical ionization mass spectrometric detection of the peroxy radical. The alkyl peroxy radicals were generated by reacting alkyl radicals w
i-C4HgON0 was photolyzed with 366-nm radiation at -8, 23, 55, 88, and 120Β°C in a static system in the presence of NO, O,, and N2. The quantum yield of i-C,H7CH0, @{i-C3H7CHO}, was measured as a function of reaction conditions. The primary photochemical act is and it proceeds with a quantum yield &