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The rate of reaction between HO2 radicals at low pressures

โœ Scribed by B.A. Thrush; G.S. Tyndall


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
270 KB
Volume
92
Category
Article
ISSN
0009-2614

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Pressure dependence of the rate of react
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Receiicd IS Jo;> 1979 r\fe33uremcnrs of the rates of the re;ftLlfln, HO1 -NO2 = H202 + 02 fff, by laser magnertc resommce spectroscopy at 298-5 Iye iielded the follotring uhy;fXSfor ficlium\_zx\_rers at ~nrious toss1 prnntres: (2.9 f 1.2) X tOei aa3 z~IOfecde 5 3c 2 Torr, t-1.3 : I.81 X LO cm moIccu

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The rate-coefficients for the reactions HO2 + NO = HO + NO\* (1) and HO\* + HO = Hz0 + 0, (2) have been remeasured by laser magnetic resonance using an improved experimental arrangement. Values of kl = (6-9 f 0.6) X lO-12 cm3 molecule-' s-l and k2 = (5.8 -c 09) X 10-l cm3 molecule-' s-' (one standar

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The molecular-modulation-UV/visibleabsorption+ectroscopy technique has been used to investigate the simultaneous time. resolved behaviour of10 and HO2 produced by the pbotolysis of O3 in the presence of CH30H, Iz, O2 and Ar. This has enabled a direct measurement of the rate coefficient for the react

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HO2 profiles in the thermal decomposition of H,02 in shock waves over the range 1000-1250 K were analyzed with respect to the reactions HO+HZOz+HOz+H20 (3) and HO+H0r~Hz0+02 (4). Reaction (3) shows a strong up-turn ofthe rate constant at temperatures near 800 K. Over the range 250-1250 K, k, can be

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Replacement of N 2 by CO in H 2 + 02 + N 2 mixtures undergoing slow reaction at 500ยฐC causes a marked increase in the reaction rate and a decrease in the induction period, expressed as the time to half maximum rate. A detailed interpretation using a computer treatment gives k24/klo 1/2 = 0.42 ยฑ 0.03