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The Rate Constant of the Reaction of Superoxide with Nitrogen Monoxide: Approaching the Diffusion Limit

โœ Scribed by Nauser, T.; Koppenol, W. H.


Book ID
127223577
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
48 KB
Volume
106
Category
Article
ISSN
1089-5639

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The remarkable nucleophilicity of supero
โœ Wayne C. Danen; R.Jay Warner ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 250 KB

We wish to report rate constants for the reaction of superoxide anion radical, 02', with various aliphatic bromides in dimethylsulfoxide (DMSO) solution. The results suggest that 02; is one of the most potent nucleophiles yet studied. Superoxide ion is the radical anion derived by adding an electro