The rate constant for the “dimol” transition of singlet oxygen, O2(a 1Δg), and the likely symmetry of the emitting species
✍ Scribed by Peter Borrell; Nathan H. Rich
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 302 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0009-2614
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The relaxation rate constants of the low-lying electronic singlet states, a '4 and b ' Z: , of gaseous natural O2 and of the isotope "O? were investigated as a function of temperature from 100 to 295 K. The measured increase of the rate constants with temperature is in good agreement with a theory o
A number of indolic compounds were studied as quenchers of singlet molecular oxygen. O&A,) generated by photosensitization. The ratio of the chemical (reactive) and physical quenching paths was a function of the substitution pattern of the quencher. Indoles substituted in position 3 gave measurable