The Arrhenius parameters for the title reaction have been measured in a very-low-pressure pyrolysis apparatus in the temperature range 644-722 K and are given by log kZ (A4-I. sec-I) = 9.68 -2.12/8, where 0 = 2.303RT in kcal/mol. Together with the published Arrhenius parameters for the reverse react
The rate constant for H + i-C4H8 → t-C4H9 in the range of 298–563 K
✍ Scribed by Carlos E. Canosa; Roger M. Marshall; Adrian Sheppard
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 304 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0538-8066
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The overall rate constant for hydrogen‐atom addition to isobutene has been measured in the temperature range of 298–563 K in a flow discharge system coupled to a quadrupole mass spectrometer. Previously published results allow the determination of
where the error limits are 95% confidence limits.
equation image
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