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The rate constant for combination of a CCl3 radical with cyclohexyl or n-hexyl radicals. An evidence for the value of the rate constant for a Cl atom transfer

✍ Scribed by Zeev B. Alfassi

Publisher: John Wiley and Sons
Year: 1980
Tongue: English
Weight: 297 KB
Volume: 12
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550120402

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✦ Synopsis

Abstract

The variation of the radiolytic yield of hexachloroethane in the system alkane + carbon tetrachloride can be used to measure the rate constant for the combination of a CCl~3~ radical with an alkyl radical. The treatment of the data for hexane and cyclohexane shows that the rate for a Cl atom transfer must be lower than the high values of Katz et al. and Tuan et al.

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