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The rate coefficients for several ternary association reactions of CH3+ in the temperature range 100–300 K

✍ Scribed by N.G. Adams; D. Smith; D.G. Lister; A.B. Rakshit; M. Tichy; N.D. Twiddy

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
453 KB
Volume
63
Category
Article
ISSN
0009-2614

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✦ Synopsis

ITIE ten:pcr.tture variation of the ttrnar.r rate coefficients for thenssociation of CHf aith Hz. CO, Ma. 02 and CO? with helium .IS Ihe stnbilitirg third body habe been studied in the range 100 I; to 300 L using a selected ion no< tube appar.dus_ The ternary rate coefficients ore found to hate an inverse-power-law tcmpcrarure dependence of the form 83 = AT-'* uith n z 3-4 over tbc tempcmture range studied. The pressure saturation of the effectire bin;try za,te rucft?cicnt for the CO rtiction 1~ b&n studied in some dctzdl.zmd the onset of pressure nruration IWS also been observed Ilt the IOWr'st imIpC=tUrcs for the tI_

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