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The Raman spectrum of polycrystalline fluorotrichloromethane

✍ Scribed by H. F. Shurvell

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
320 KB
Volume
1
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

Raman spectra of polycrystalline films of CFCl~3~ have been recorded at 77K. Chlorine isotope splittings have been observed for four of the six fundamentals in agreement with predictions. The degenerate Cο£ΏCl stretching band Ξ½~4~ shows evidence of both site and factor group splitting and possibly LO and TO components. To account for the observed splittings it is suggested that solid CFCl~3~ has a non‐centrosymmetric orthorhombic crystal structure at 77K.

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