The radical copolymerization of α-substituted vinyl phosphonates
✍ Scribed by Ya.A. Levin; G.B. Fridman; V.Sh. Gurskaya; L.Kh. Gazizova; S.V. Shulyndin; B.Ye. Ivanov
- Book ID
- 118967273
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 401 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0032-3950
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Radical copolymerization of some methyl a-acyloxyacrylates and vinyl monomers has been studied using an azo initiator in benzene at 60 °C. It is found that the Q and e values of methyl a-acyloxyacrylates are in the ranges 0.47±1.65 and 0.51±0.99, respectively, and the relative reactivity of the acry
The a-substituted phosphonates (OCH 2 CMe 2 CH 2 O)P(O)CH(X)(Ar) [X=Cl, OMe, NMe 2 and OSiMe 3 ], useful precursors for Horner-Wadsworth-Emmons reactions, are readily prepared by treating (OCH 2 CMe 2 CH 2 O)PX with an aromatic aldehyde. In the reaction of (OCH 2 CMe 2 CH 2 O)PCl with furfuraldehyde