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The Radical Cation of Bicyclopropylidene: ESR Spectrum, Structure, and Reaction Products

โœ Scribed by Gerson, Fabian; Schmidlin, Reto; de Meijere, Armin; Spaeth, Thomas


Book ID
126187837
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
461 KB
Volume
117
Category
Article
ISSN
0002-7863

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The radical cation of naphthalene: First
โœ Fabian Gerson; Xue-Zhi Qin ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 399 KB

The radical cations of naphthalene (1) and its 1,6dideutero derivative (l-d,). generated from the corresponding neutral compounds by y-rays in a CFCI, matrix at 77 K, have been studied by ESR and ENDOR spectroscopy. At 140 K, the hyperfineanisotropy tensors of the protons in I+' appear to be quasi-a