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Structure and reaction of methylcyclohexane radical cation: ESR studies

โœ Scribed by Masaru Shiotani; Nobuaki Ohta; Takahisa Ichikawa

Book ID
107733267
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
487 KB
Volume
149
Category
Article
ISSN
0009-2614

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ESR evidence of a distorted 2Ag electron
ESR evidence of a distorted 2Ag electronic structure for the methylcyclohexane radical cation
โœ Mikael Lindgren; Masaru Shiotani; Nobuaki Ohta; Takahisa Ichikawa; Lars Sjoqvist ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 341 KB

The electronic structure of the methylcyclohexane (Me-cc,) radical cation has been investigated by ESR in a perfluoromethylcyclohexane matrix at 4 K. The ESR spectrum of Me-&s+ consists of a triplet of doublets with signals at z 74 G (2H) and sz 34 G ( 1H). With the aid of two selectively deuteriate