The potential curves for the X 'II, A %+ and B 2A states of the CF molecule have been determined using large Gaussian basis sets and accounting for electron correlation with the CASSCF/multireference CI method. The transition moment function between the X \*II and A %+ state is found to undergo a dr
The radiative lifetime of CF(A 2Σ+)
✍ Scribed by J.P. Booth; G. Hancock
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 337 KB
- Volume
- 150
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
RADIATIVE LIFETIME OF METASTABLE NH(b 'Z') U. BLUhlENSTEIN, F. ROHRER and F. STUHL Rcccivcd 26 \!arch 1981 The radiative lil'ctinw of mctaztablc NH@ lx+) \\a dctcrmincd to bc 53;': rns us,"; VU\' flash photoly,l> of SHs and ArF laser photolyk of HS,. For the transitions IO IIIC INO componcn~s. 3X,,
Calculations using large atomic natural orbital (ANO) basis sets and high levels of correlation treatment are employed to determine the radiative lifetime for the t= I-5 levels of the X 'Z+ state ofNO+. The theoretical lifetimes, which agree well with prewous theoretical estimates, are estimated to
PH (b 'C? has been obtained in the vacmzm ultravioiolet flash photolysis of PH3 and detected by the 697.3 nm emission due to the forbidden transition PH (b 'Z \* -+ X 3Z-). Rate coefficients for mdiitive and collisional deactivatioa have been determined by time resolved measurements. A radiative Iif