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The question of an open-ring form of cyclopropanone

✍ Scribed by John F. Olsen; Sungzong Kang; Louis Burnelle


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
815 KB
Volume
9
Category
Article
ISSN
0022-2860

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An Unusual Opening of the Pinane Ring
✍ Rodney M. Giddings; David Whittaker πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 105 KB

The ring opening and ring expansion reactions of a-pinene (I, Me substituent on C-2) have been extensively studied using thermal, acid catalysis and heterogeneous catalysis methods. In all cases, reaction takes place by shift or fission of the C-l to C-6 bond, since the gem-dimethyl group provides s