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An Unusual Opening of the Pinane Ring

✍ Scribed by Rodney M. Giddings; David Whittaker

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
105 KB
Volume
19
Category
Article
ISSN
0040-4039

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✦ Synopsis

The ring opening and ring expansion reactions of a-pinene (I, Me substituent on C-2) have been extensively studied using thermal, acid catalysis and heterogeneous catalysis methods. In all cases, reaction takes place by shift or fission of the C-l to C-6 bond, since the gem-dimethyl group provides stabilisation of the intermediates involved.

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