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The quantum numbers of the fluorescent state of the uranyl ion

✍ Scribed by Christian K. Jørgensen; Renata Reisfeld

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
306 KB
Volume
35
Category
Article
ISSN
0009-2614

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✦ Synopsis

A close analysis of the relative importuce of spin-orbit coupling and of one-electron cncrg ditfcrenccs in the 5f shell, combined with spectroscopic data on uranyl ions in glasses and crystals, suggsts the lowest excited level to have R = 3, even parity and no ~vcli-dciined S nnd A.

📜 SIMILAR VOLUMES

Do higher excited states of the uranyl i
Do higher excited states of the uranyl ion luminesce?
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We examine a report that emission can be observed from excited states of the uranyl ion, above that giving the usual green emission, in the light of new measurements. We can find no firm evidence for emission from such states.

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✍ C. Görller-Walrand; W. Colen 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 212 KB

The literature indicates a four-fold or su-fold coordination symmetry for \(\mathrm{UO}_{2}^{2+}\) in aqueous solution However, the uranyl ion in erystalline \(\mathrm{UO}_{2}\left(\mathrm{ClO}_{4}\right)_{2} 7 \mathrm{H}_{2} \mathrm{O}\) has been found by \(\mathrm{X}\)-ray diffraction to be coordi