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The pyrolysis of CCl4 and C2Cl6 in the gas phase. Mechanistic modeling by thermodynamic and kinetic parameter estimation

✍ Scribed by G. Huybrechts; M. Narmon; B. Van Mele

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 653 KB
Volume: 28
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1996)28:1<27::aid-kin4>3.0.co;2-o

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✦ Synopsis

A detailed radical reaction mechanism is proposed to describe the thermal reactions of CCI4 and C2CI, in the gas phase quantitatively A consistent set of activation energies and preexponential factors for all elementary reactions, in combination with enthalpies of formation and entropies for all species involved, I S computer optimized to fit experimental pressure-rise curves and concentration profiles.

For this purpose new experimental results on the pyrolysis of CCI4 are used, together with published kinetic data on the pyrolysis of C2CII, ( i n the absence and in the presence of CI2)

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