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Pyrolysis of hexachloroethane in the gas phase: Computer aided kinetic study

✍ Scribed by G. Huybrechts; J. Theys; B. Van Mele

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 331 KB
Volume: 28
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1996)28:10<755::aid-kin6>3.0.co;2-m

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✦ Synopsis

The pyrolysis of C,CI, has been studied between 652 and 735 K at pressures ranging from 19 to 50 torr. The observed total pressure-and CI, pressure-time curves show S-shapes with an induction period depending on temperature and pressure Further, the total pressure goes through a maximum to finally reach a lower constant value. These curves are explained in terms of a recently proposed reaction model using a parameter optimization computer program

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