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Gas-phase pyrolysis of 2-heteroaromatic-1-dimethylaminoethylenes: Kinetic and mechanistic study

✍ Scribed by Mohamed H. Elnagdi; Nouria A. Al-Awadi; Agith Kumar; Mervat Abdul Khalik

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 89 KB
Volume: 12
Category: Article
ISSN: 1042-7163
DOI: 10.1002/1098-1071(2001)12:1<47::aid-hc10>3.0.co;2-q

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✦ Synopsis

Gas-phase pyrolysis reactions of 4(2Ј

) (Scheme 1) have been carried out. The rates of gas-phase pyrolytic reactions of compounds 3, 4, 5, and 7 have been measured and found to correspond to unimolecular first-order reactions. Product analyses together with kinetic data were used to outline a feasible pathway for the pyrolytic reactions of the compounds under study.

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