The pyrolysis of acetylene
β Scribed by Minkoff, G. J.; Newitt, D. M.; Rutledge, P.
- Book ID
- 126909074
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 78 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0021-8871
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π SIMILAR VOLUMES
The kinetics of acetylene polymerization initiated by neopentane (Np) or acetone (Ac) decompositions has been investigated in a static reactor dynamically coupled to a modulated beam mass spectrometer between 850-950 K. Overall rates follow the expres- LC2H,12 (I), where X represents Np or Ac and k,
## Abstract The polymerization of acetylene below 550Β° has been examined in a static system. For unpacked vessels it was found possible to obtain reproducible results, from which secondβorder rate constants, and an activation energy of 46Β·7 | 2 kcal., have been obtained. The effect of a large numbe
This comment refers to the recent article of this title by S. W. Benson [ll, in which he returns to an H-atom chain mechanism for the low-temperature acetylene pyrolysis. That article contains a fairly complete chain mechanism and a critique of the alternative molecular (vinylidene) scheme proposed