✦ LIBER ✦

The Proton Cryptate of Hexaethylenetetramine

✍ Scribed by Yuji Miyahara; Yurika Tanaka; Kiichi Amimoto; Takamitsu Akazawa; Tsutomu Sakuragi; Haruhito Kobayashi; Kazuomi Kubota; Masahiko Suenaga; Hiroyuki Koyama; Takahiko Inazu

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 181 KB
Volume: 38
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19990401)38:7<956::aid-anie956>3.0.co;2-k

No coin nor oath required. For personal study only.

✦ Synopsis

The next higher homologue of hexamethylenetetramine was synthesized as the proton cryptate H @1⋅Br (shown schematically), and its X-ray structure determined. The proton trapped by the lone pairs accumulated at the center of the T-symmetric tetraaza cage could not be exchanged or removed, even after heating for three days in 3 M NaOD.

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