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Proton and Hydrogen Affinity of Furan and the Site of Protonation in the Gas Phase

✍ Scribed by Dr. Raymond Houriet; Prof. Dr. Helmut Schwarz; Waltraud Zummack

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
230 KB
Volume
19
Category
Article
ISSN
0044-8249

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✦ Synopsis

Ion cyclotron resonance measurements on D‐labeled furan revealed that in the prototype electrophilic reactionsβ€”i.e. protonationβ€”furan behaves in the gas phase as a typical arene and not as enol ether.

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The chemical ionization mass spectra of polyamines have been used to determine the importance of competing intramolecular reactions of protonated molecules in the gas phase. Multifunctional molecules react if possible in the order of intramolecular displacement-cyclization reactions, stabilization o