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The products of the reaction of the hydroxyl radical with 2-ethoxyethyl acetate

✍ Scribed by J. R. Wells; Floyd L. Wiseman; Dale C. Williams; J. Steven Baxley; D. F. Smith

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 448 KB
Volume: 28
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1996)28:7<475::aid-kin1>3.0.co;2-s

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✦ Synopsis

The gas-phase reaction products of the OH radical with 2-ethoxyethyl acetate (EEA, CH3C(O]OCH,CH,0CH,CH3] have been investigated. I ,2-Ethanediol acetate forrnate [ EAF, CH,C(O)OCH,CH,OC(O)H) and ethyl formate (EF, HC[O)OCH,CH,) were identified as the two main products A third product, ethylene glycol diacetate (EGD, CH,C(0)OCH,CH,0C(O)CH3), was also observed EAF, EF, and EGD formation yields were determined to be 0.37 2 0.03 and 0 328 2 0.018 and 0 040 2 0 005, respectively. Proposed reaction mechanisms are discussed and compared with these data 0 1996 john Wiley & Sons. Inc.

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