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The Preparation of Some Tertiary Alcohols by the Addition of Organic Acids to Grignard Reagents

✍ Scribed by Huston, Ralph C.; Bailey, Donald L.

Book ID
126120403
Publisher
American Chemical Society
Year
1946
Tongue
English
Weight
272 KB
Volume
68
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Cerium chloride-promoted nucleophilic ad
Cerium chloride-promoted nucleophilic addition of grignard reagents to ketones an efficient method for the synthesis of tertiary alcohols
✍ Tsuneo Imamoto; Nobuyuki Takiyama; Kimikazu Nakamura πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 248 KB

In the presence of anhydrous cerium(III1 chloride, Grignard reagents react with ketones to afford addition products in high yields, even though the substrates are susceptible to abnormal reactions with Grignard reagents alone. ## The reaction of Grignard reagents with carbonyl Sympounds is well-k