A new fullerene self-assembled monolayer (SAM) which has the property of photoelectric conversion is reported here. The SAM was fabricated on hydrophilic substrates by an esterification reaction. The SAM is characterized by contact angle, AFM, UV spectrum, and cyclic voltammetry. A cathodic photocur
The preparation of oxygenated fullerene film and its photoelectrical properties
β Scribed by Wook Cho; Sung-Chae Yang
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 490 KB
- Volume
- 202
- Category
- Article
- ISSN
- 0257-8972
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β¦ Synopsis
In studies of photoelectrochemical properties of C 60 thin films, researchers have pointed out that the presence of oxygen in C 60 thin films causes problems in electron and hole drift mobilities as well as in the recombination lifetime at a moderate steady-state illumination level; therefore, it is necessary to understand the characterization of photoelectronic and transport processes in oxygenated C 60 thin films. From previous studies, researchers have pointed out that C 60 fullerene thin film has the n-type property. Therefore, by using oxygenated C 60 fullerene thin film, we prepared p-n junctions (C 60 /p-Si) in order to obtain its photoelectronic conversion properties. We analyzed the conductivity, the I-V curves, the open-circuit voltage and close-circuit current versus film thickness, and the fill factor and conversion efficiency. As a result, we found the photoelectronic conversion properties of the p-n junctions (C 60 /p-Si). However, the photoelectronic properties of n-type C 60 fullerene thin film are lower than the characteristics of other photoelectronic devices. Those that have low photoelectronic conversion properties have the possibility of being good photoelectronic devices. Therefore, C 60 fullerene thin film can be applied to photoelectronic device fields.
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