The preparation of group IV organometallic compounds containing gem-dihalocyclopropyl groups
β Scribed by Dietmar Seyferth; Theodore F. Jula; Hadwig Dertouzos; Michel Pereyre
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 878 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-328X
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## Abstract Iodine cleavage of the metalβmetal bond in hexasubstituted dimetals of the fourth group has been studied kinetically. The reactivities of disiliciums, digermaniums, ditins and mixed dimetals are discussed in function of the substituents and of the metals involved in the metalβmetal bond
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Part 4. Synthesis of Compounds Containing Vicinal gem-Dinitro Groups. -Nitration of Ξ²-methyl-Ξ³,Ξ³-dinitroketones (III) and (V) proceeds by C-C bond cleavage to afford compounds (IV) and (VI), resp., containing two vicinal gem-dinitro groups. The tetranitrohexanoic acid (VI) is used for the synthesis