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The preparation of germanium-transition metal complexes from trichlorogermanate — metal carbonyl reactions

✍ Scribed by J.D. Cotton; R.M. Peachey


Publisher
Elsevier Science
Year
1970
Weight
189 KB
Volume
6
Category
Article
ISSN
0020-1650

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Carbonylation of Transition-Metal Carbyn
✍ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 2 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and −30°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60°C and under 60atm pre