The preparation of 1,2-Dithiols from episulfides
✍ Scribed by J.M. Lalancette; M. Laliberté
- Book ID
- 104246886
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 172 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Potassirim carbonate. mediated methanol?isis of opticalh. actiiie ~,3-oxathiolane-2-thiones (5-membered c?clic xanthates) took place under v e p mild conditions to gii,e opticall? pure 1,2-episulfides. Also, methanol?sis of'3-[1-iiizetha,iesulfon~lox~)alk?~~-l,3-oxathiola1ie-2-thiones and 2,d-dialky
For the first time, episulfones have been prepared by oxidation of the corresponding episulfides. Seven examples are given, most of which proceed in good to excellent yield, The first oxidation of an episulfoxide to an episulfone is also repotted as part of a preliminary mechanistic study.