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The first preparation of episulfones from episulfides: Oxidation using oxone®/trifluoroacetone

✍ Scribed by Paul Johnson; Richard J.K. Taylor

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
261 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

For the first time, episulfones have been prepared by oxidation of the corresponding episulfides. Seven examples are given, most of which proceed in good to excellent yield, The first oxidation of an episulfoxide to an episulfone is also repotted as part of a preliminary mechanistic study.

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