As part of a programme involving X-ray crystallographic studies" of cis-and tpuns-fused hexopyranosides, we now report on the crystal structures of methyl 2-~-methyl-~-D-glucop~anoside\* (11, which was obtained by debe~lidenation of methyl 4,~-O-benzyIidene-2-O-methyI-3-O-~-tolylsulfonyl-~-~-glucopy
The preparation and x-ray crystallographic characterisation of methyl 4,6-O-benzylidene-2,3-di-C-methyl-2-O-(methylthio)methyl-α-d-allopyranoside, and its conversion into methyl 2,3-dideoxy-2,3-di-C-methyl-α-d-glycero-hexopyranosid-4-ulose
✍ Scribed by Vernon G.S. Box; Lynda L. Box; Earle V.E. Roberts; John F. Blount; Louis J. Todaro
- Book ID
- 107725237
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 522 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0008-6215
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Condensation of 2,4-di-O-acetyl-3,6-di-O-methyl-a-~glucopyranosyl bromide with either ally1 or benxyl2,4-di-0-methyl-cu+rhamnopyranoside in the presence of mercuric cyanide, followed by 0-deacetylation, gave the title oligosaccharides in excellent yields.