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The preparation and study of polycarbonates—V. Polycarbonates from 2,2-di-(4-hydroxy-3,5-dibromophenyl) propane and phosgene

✍ Scribed by I.P. Losev; O.V. Smirnova; Ye.V. Korovina


Book ID
118356371
Publisher
Elsevier Science
Year
1964
Weight
346 KB
Volume
5
Category
Article
ISSN
0032-3950

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The new cyclic carbonate monomer 2,4,8,10-tetraoxaspiro [5,5]undecane-3one (DOXTC) was prepared in ú 80% yield by the reaction of 1,3-dioxane-5,5-dimethanol with ethyl chloroformate in tetrahydrofuran (THF). DOXTC homopolymerization and copolymerizations with trimethylene carbonate (TMC) were carrie