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The Preparation and Structures of Group 12 (Zn, Cd, Hg) Complexes of the Soft Tripodal Ligand Hydrotris(methimazolyl)borate (Tm)

✍ Scribed by Iain Cassidy; Mark Garner; Alan R. Kennedy; Graeme B. S. Potts; John Reglinski; Paul A. Slavin; Mark D. Spicer


Book ID
101347890
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
256 KB
Volume
2002
Category
Article
ISSN
1434-1948

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Metal–Metal Bonds between Group 12 Metal
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Reaction of the lithium triamidostannate [MeSi[SiMe(2)N(p-Tol)](3)SnLi(OEt(2))] (1) with 0.5 molar equivalents of MCl(2) (M=Zn, Cd, Hg) in toluene afforded the corresponding heterodimetallic complexes [MeSi[SiMe(2)N(p-Tol)](3)Sn](2)M [M=Hg (2), Cd (3), and Zn (4)]. The molecular structures of the me